Description
A Round Bottom (R/B) Boiling Flask, often referred to as a “Florence Flask” or “Spherical Flask,” is the workhorse of organic chemistry and distillation. Its unique spherical shape is engineered for high-stress environments, providing superior resistance to heat and pressure compared to flat-bottomed alternatives.
Key Product Features
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Superior Heat Distribution: The spherical body allows heat to circulate evenly throughout the liquid. This prevents “hot spots” and minimizes the risk of thermal shock or “bumping” (sudden, violent boiling).
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High Structural Integrity: Because it h
- as no flat surfaces or sharp angles, it distributes mechanical stress evenly. This makes it the only safe choice for vacuum-distillation and applications involving internal pressure.
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Borosilicate 3.3 Material: Highly resistant to chemical erosion and capable of withstanding temperatures up to 500°C. It features a very low coefficient of thermal expansion.
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Neck Variations:
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Plain Neck: Features a reinforced beaded rim for use with rubber stoppers.
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Ground Glass Joint: Features a precision-ground joint (e.g., 24/29 or 29/32) to create an airtight, grease-free seal with condensers, separatory funnels, or fractionating columns.
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Technical Specifications
| Capacity (ml) | Body Diameter (mm) | Neck Diameter / Joint | Approx. Height (mm) |
| 50 | 50 | 19/26 or 24/29 | 90 |
| 100 | 65 | 24/29 | 110 |
| 250 | 85 | 24/29 or 29/32 | 145 |
| 500 | 105 | 24/29 or 29/32 | 175 |
| 1000 (1L) | 130 | 29/32 | 210 |
| 2000 (2L) | 165 | 29/32 | 260 |
Primary Applications
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Distillation & Reflux: Used as the primary heating vessel where vapors are generated and then cooled in a condenser.
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Evaporation: Often used in Rotary Evaporators (Rotovaps) to remove solvents from samples under reduced pressure.
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Chemical Synthesis: Ideal for long-duration reactions that require constant heating (boiling) and stirring.
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Vacuum Applications: Safely holds contents under vacuum conditions where a flat-bottom flask might implode.
Support & Handling
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Support Requirements: Since the flask cannot stand upright, it must be supported by:
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Cork/Rubber Rings: For resting on a lab bench.
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Heating Mantles: Which wrap around the sphere for precise, even temperature control.
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Clamps: To secure the neck to a retort stand.
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Safety Tip: When heating a round-bottom flask over a direct flame (Bunsen burner), always use a wire gauze or a sand bath to further diffuse the heat.
Why Choose R/B over F/B?
While Flat Bottom (F/B) flasks are convenient for sitting on a hotplate, the Round Bottom (R/B) is the professional choice for serious chemistry. Its ability to handle vacuum pressures and its shatter-resistant geometry make it indispensable for any procedure involving distillation or high-intensity thermal reactions.

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